Typical PES (UPS) instruments use helium gas sources of UV light, with photon energy up to 52 eV (corresponding to wavelength 23.7 nm). The photoelectrons that actually escaped into the vacuum are collected, slightly slowed down, energy resolved, and counted.OverviewPhotoemission spectroscopy (PES), also known as photoelectron spectroscopy, refers to energy or measurement of emitted from solids, gases or liquids by the, in order to determine the. (XPS) was developed by starting in 1957 and is used to study the energy levels of atomic core electrons, primarily in solids. Siegbahn referred to the technique as "electron s. The physics behind the PES technique is an application of the. The sample is exposed to a beam of UV or XUV light inducing photoelectric ionization. The energies of the emitted photoelectrons are charact.